| | 1 | 1 |  Vicky MacIntosh Danél Louw | 30-34 | 00:55:02 | |
| | 2 | 2 | Andrea Erasmus Carien Fourie | 30-34 | 01:03:25 | |
| | 3 | 1 | Stephani van Zyl Margot Rademeyer | 25-29 | 01:06:13 | |
| | 4 | 2 | Octavia De Sa Tatiana Martins | 25-29 | 01:06:54 | |
| | 5 | 1 | Melissa Clarke Shani De Witt | 35-39 | 01:07:00 | |
| | 6 | 3 | Heléne Coetzer Lara Bruwer | 30-34 | 01:07:10 | |
| | 7 | 4 | Uleen Fourie Bernette Bester | 30-34 | 01:07:47 | |
| | 8 | 3 | Olivia Gearing Sasha Domnick | 25-29 | 01:08:11 | |
| | 9 | 1 | Isabella Winter Ashton Weir | 16-24 | 01:08:55 | |
| | 10 | 2 | Riana Van Heerden Michaela Meintjes | 35-39 | 01:10:34 | |
| | 11 | 3 | Bronwyn Shand Abigail Keats | 35-39 | 01:10:56 | |
| | 12 | 4 | Ashleigh Botha Morgen-Emma Reed | 35-39 | 01:12:33 | |
| | 13 | 5 | Marchanne De Bruyn Nikki Carter | 30-34 | 01:12:37 | |
| | 14 | 1 | Claudia Hazelwood Laura Smal | 40-44 | 01:13:38 | |
| | 15 | 4 | Lucinda Bosch Danielle Jordaan | 25-29 | 01:13:52 | |
| | 16 | 2 | Lane Du Plessis Susan Buys | 40-44 | 01:14:27 | |
| | 17 | 5 | Chrisna Campher Jenna Yeats | 35-39 | 01:14:35 | |
| | 18 | 3 | Natalie Agostinho Amy Cohen | 40-44 | 01:15:21 | |
| | 19 | 6 | Rezelle Secchia Miranda Beringer | 35-39 | 01:16:00 | |
| | 20 | 2 | Tatijana Ignjatov Vesna Ignjatov | 16-24 | 01:17:04 | |
| | 21 | 7 | Phelisa Mtsewu  Pressya Ndongala | 35-39 | 01:17:26 | |
| | 22 | 4 | Elshe Naude Mel De Morny | 40-44 | 01:18:18 | |
| | 23 | 1 | Zsuzsanna Gyorgy Mar-Loes Mantoua | 45-49 | 01:19:23 | |
| | 24 | 2 | Claudia Monteiro Lee-Ann Johns | 45-49 | 01:20:51 | |
| | 25 | 8 | Neliswe Biyela Kausar Shaik | 35-39 | 01:22:01 | |
| | 26 | 9 | Rebecca Jopson Natasha Shaw | 35-39 | 01:22:49 | |
| | 27 | 5 | Lisa Mari Le Roux Lize-Marie Vermeulen | 25-29 | 01:23:26 | |
| | 28 | 5 |  Ludivine Huet-Haupt Tracey-Lee Johnson | 40-44 | 01:23:27 | |
| | 29 | 6 | Beverley Siwisa Georgia Love | 40-44 | 01:24:07 | |
| | 30 | 6 | Tyler Spence Samantha Wittmann | 25-29 | 01:29:31 | |
| | 31 | 1 | Monica Dowie Marisa Marais | 50-54 | 01:33:29 | |
| | 32 | 3 | Anna Calivitis-Barnard Matina Barnard | 16-24 | 01:42:08 | |
| | 33 | 10 | Melissa Reyneke Gabrielle D'Arch | 35-39 | 01:42:18 | |
| | 34 | 11 | Zimkhitha Nazo Zanele Booi | 35-39 | 01:46:12 | |
| | 35 | 12 | Nontobeko Nyalunga Sibabalwe Mgijima | 35-39 | 01:47:11 | |
| | 36 | 7 | Nosipho Sijula Siyasanga Grace Tabata | 25-29 | 01:48:29 | |
| | 37 | 3 | Babalwa Fede  Suratsawadi Mart | 45-49 | 02:08:45 | |
| | 38 | 7 | Nonhlanhla Dlamini Nomonde Kralo | 40-44 | 02:12:07 | |
| | 39 | 6 | Yamkela Mroqo Lelethu Magula | 30-34 | 02:17:16 | |
| | 40 | 13 | Cordelia Masemola Pearl Kgosimmele | 35-39 | 02:34:35 | |
| | 41 | 8 | Nicolene Erasmus Karen van Wyk | 40-44 | 02:36:20 | |
