| 1 |  Danél Louw Vicky MacIntosh | 30-34 | 03:51 | |
| 2 | Octavia De Sa Tatiana Martins | 25-29 | 03:54 | |
| 3 | Abigail Keats Bronwyn Shand | 35-39 | 03:55 | |
| 4 | Michaela Meintjes Riana Van Heerden | 35-39 | 03:57 | |
| 5 | Heléne Coetzer Lara Bruwer | 30-34 | 04:02 | |
| 5 | Tatijana Ignjatov Vesna Ignjatov | 16-24 | 04:02 | |
| 7 | Bernette Bester Uleen Fourie | 30-34 | 04:05 | |
| 8 | Chrisna Campher Jenna Yeats | 35-39 | 04:06 | |
| 8 | Lane Du Plessis Susan Buys | 40-44 | 04:06 | |
| 10 | Claudia Hazelwood Laura Smal | 40-44 | 04:07 | |
| 10 | Margot Rademeyer Stephani van Zyl | 25-29 | 04:07 | |
| 10 | Marchanne De Bruyn Nikki Carter | 30-34 | 04:07 | |
| 13 | Andrea Erasmus Carien Fourie | 30-34 | 04:10 | |
| 14 | Olivia Gearing Sasha Domnick | 25-29 | 04:11 | |
| 14 | Ashton Weir Isabella Winter | 16-24 | 04:11 | |
| 16 | Melissa Clarke Shani De Witt | 35-39 | 04:12 | |
| 17 | Danielle Jordaan Lucinda Bosch | 25-29 | 04:16 | |
| 18 | Lisa Mari Le Roux Lize-Marie Vermeulen | 25-29 | 04:18 | |
| 19 | Kausar Shaik Neliswe Biyela | 35-39 | 04:20 | |
| 20 | Elshe Naude Mel De Morny | 40-44 | 04:24 | |
| 20 | Beverley Siwisa Georgia Love | 40-44 | 04:24 | |
| 22 | Miranda Beringer Rezelle Secchia | 35-39 | 04:25 | |
| 23 | Ashleigh Botha Morgen-Emma Reed | 35-39 | 04:27 | |
| 24 | Natasha Shaw Rebecca Jopson | 35-39 | 04:32 | |
| 24 | Samantha Wittmann Tyler Spence | 25-29 | 04:32 | |
| 24 |  Ludivine Huet-Haupt Tracey-Lee Johnson | 40-44 | 04:32 | |
| 27 | Mar-Loes Mantoua Zsuzsanna Gyorgy | 45-49 | 04:34 | |
| 28 | Phelisa Mtsewu  Pressya Ndongala | 35-39 | 04:35 | |
| 29 | Gabrielle D'Arch Melissa Reyneke | 35-39 | 04:37 | |
| 30 | Amy Cohen Natalie Agostinho | 40-44 | 04:39 | |
| 31 | Nontobeko Nyalunga Sibabalwe Mgijima | 35-39 | 04:41 | |
| 32 | Nosipho Sijula Siyasanga Grace Tabata | 25-29 | 04:50 | |
| 33 | Anna Calivitis-Barnard Matina Barnard | 16-24 | 04:51 | |
| 34 | Claudia Monteiro Lee-Ann Johns | 45-49 | 04:56 | |
| 34 | Babalwa Fede  Suratsawadi Mart | 45-49 | 04:56 | |
| 36 | Marisa Marais Monica Dowie | 50-54 | 04:57 | |
| 37 | Karen van Wyk Nicolene Erasmus | 40-44 | 05:07 | |
| 37 | Nomonde Kralo Nonhlanhla Dlamini | 40-44 | 05:07 | |
| 39 | Zanele Booi Zimkhitha Nazo | 35-39 | 05:11 | |
| 40 | Cordelia Masemola Pearl Kgosimmele | 35-39 | 05:19 | |
| 41 | Lelethu Magula Yamkela Mroqo | 30-34 | 05:29 | |
