| 100 |  Cristina Navarro Rodríguez Pedro Martínez Torrecillas | 40-49 | 04:38 40-49 | |
| 102 | Marcela Bulmaga Mario Sánchez González | 30-39 | 04:39 30-39 | |
| 103 | Federica Catalano Pablo Espinosa García | 30-39 | 04:40 30-39 | |
| 104 | German Payeras Marcati Yolanda Veny Villanueva | 40-49 | 04:41 40-49 | |
| 105 | Agustin Saiz Marin Silvia Navarro Solvas | 50-59 | 04:42 50-59 | |
| 106 | Jose Manuel Sanes Linares Loreto Irene Rico Bonmatí | 30-39 | 04:44 30-39 | |
| 106 | Manuel Villar Aparicio Marta Pujol Escudero | 16-29 | 04:44 16-29 | |
| 108 |  Rui Pinheiro Susana Torres | 40-49 | 04:45 40-49 | |
| 108 | Jose Manuel Luque Reglero Margarita Moragues Tur | 40-49 | 04:45 40-49 | |
| 110 | Joaquin Borja De Thomas Gomez Mira Marasigan | 30-39 | 04:46 30-39 | |
| 111 | Francisco Javier Lendínez Tirado Nieves Pérez Castro | 16-29 | 04:47 16-29 | |
| 112 |  Rühl Stefan Thürbeck Julia | 30-39 | 04:48 30-39 | |
| 113 | Javier Caldeiro García Luna Dos Anjos Stamatis | 30-39 | 04:50 30-39 | |
| 114 | Celia Gálvez Domingo Juan Jose Vivancos | 30-39 | 04:52 30-39 | |
| 114 | Ana María Nicolás Manzanares Gabriel Delgado Fernández | 30-39 | 04:52 30-39 | |
| 116 | Consuelo Pérez Piera Juan Ferrer López | 30-39 | 04:58 30-39 | |
| 117 | David Ferrando López Marina Gallego I Pérez | 30-39 | 05:07 30-39 | |
| 117 | María Jesús Arenas Merlo Txus Macías | 50-59 | 05:07 50-59 | |
| 119 | Carlos García Consuegra Maite Martínez Orts | 30-39 | 05:10 30-39 | |
